Reproductive toxicity specific target organ toxicity single or. Irritation skin or eyes skin sensitization acute toxicity harmful specific target organ toxicity single exposure drowsiness or dizziness, or respiratory irritation hazardous to the ozone layer. Hazard statements are one of the key elements for the labelling of containers under the ghs, along with. Grantee materials by topic occupational safety and. Ghs, the globally harmonized system of classification and labeling of chemicals, was developed by the united nations as a way to bring into agreement the chemical regulations and standards of different countries. Ghs includes criteria for the classification of health, physical and environmental hazards, as well as specifying what information. The diamondshaped pictograms indicate the nature of the hazards associated with the use of a hazardous substance or mixture. Hazard pictograms according to clp regulation msds europe.
European msds precautionary pictograms free pdf ebook. Signal words a signal word indicates to the reader if a hazard is generally more severe or less severe. Platinumdivinyltetramethyldisiloxane complex in xylene. Convey health, physical and environmental hazard information, assigned to a ghs hazard class and category. Oct 14, 2014 hazard pictograms form part of the globally harmonized system of classification and labeling of chemicals ghs.
Keep away from heat, sparks, flames or hot surfaces. The most noticeable feature is the change in the labeling symbols. A consolidated list with translations into other eu languages was found in directive 200159ec see the links section. The clp regulation entered into force on 20 january 2009. Defines physical, health and environmental hazards of.
Hazard communication standard pictogram hcs pictograms. Hazard statements describe the nature of the chemical hazard. Ghs the new system for the classification and labeling. Pictograms serve to attract attention to the hazard warnings.
Intro to the globally harmonized system of classification and. Hazard communication standard pictogram hcs pictograms and. Clp compliant label ghs label information requirements. Platinumdivinyltetramethyldisiloxane complex in xylene safety data sheet print date. Beneath each pictogram is a listing of hazard categories represented by the corresponding image. A hazard pictogram is an image on a label that includes a warning symbol and specific colours intended to provide information about the damage a particular substance or mixture can cause to our health or the environment. Consumer understanding of the safety label and pictograms on.
The globally harmonized system of classification and labelling of chemicals ghs is a system developed by the united nations for standardizing and harmonizing the classification and labelling of chemicals globally. The minimum size of the pictograms is no more determined by the section 1. Gas 1 danger h220 extremely flammable gas category 2 flam. Pictograms will have a black symbol on a white background with a red diamond frame.
Hazard communication hazcom and the globally harmonized system of classification and labeling of chemicals ghs pennsylvania technical asst. The ghs is a system for standardizing and harmonizing the classification and labeling of chemicals. Pdf hazard communication standard pictogram quickcard osha 3491 2016 english. Code hazard statements hazard class category signal word pictogram pcodes h200 unstable explosive explosives unstable explosive danger p201, p202, p281, p372, p373, p380, p401, p501 h201 explosive. Gas 2 no pictogram warning h221 flammable gas category a chem. Globally harmonized system of classification and labelling. Find surveys, regulations and standards, risk assessment tools, frequent hazards at work and more about workplace safety and health. A hazard pictogram is intended to provide information about the hazard that can cause damage to human health or the environment. It has still to be implemented by the european union clp regulation in 2009.
Hazard pictograms ghs symbols creative safety supply. Guidance on labelling and packaging in accordance with. Hazard communication standard pictogram the hazard communication standard hcs requires pictograms on labels to alert users of the chemical. Whmis pictograms, hazard classes, and hazard categories. The european union s 2009 classification, labelling and packaging clp regulation introduced new warning pictograms. Laboratory data guides the global harmonized system ghs codes and pictograms h200 physical hazards h200 unstable explosive h201 explosive. Clp pictograms a hazard pictogram is an image on a label that includes a warning symbol and specific colours intended to provide information about the damage a particular substance or mixture can cause to our health or the environment. The exploding bomb pictogram commonly indicates explosives, but it also includes substances and mixtures that are selfreactive, which can react explosively to even the most minor of physical shocks, or even a slight increase in air pressure. However, the signal word, precautionary statements, and pictogram s must be located together on the label. Globally harmonized system ghs hazard communication safety data sheets quickcard osha 3493 2016 english.
List of ghs hazard and precautionary statements precautionary statements general precautionary statements p101. The hazard symbols for chemicals were defined in annex ii of directive 67548eec. Signal code hazard statements hazard class category pictogram. Accordingly, the classification of your substance or mixture determines the hazard pictograms that should be displayed on your label, for example. Two sets of pictograms are included within the ghs. Either one or the other is chosen, depending on the target. Html pdf add to cart hazard communication standard labels quickcard osha 3492 2016 english. Hazard pictograms a hazard pictogram is a pictorial presentation of a particular hazard. However, users are reminded that the text of the clp regulation is the only authentic legal reference and that the information in this document does not constitute legal advice. The newlyrequested pictogram must be approved by these regulatory bodies before its use in any submission under the terms of this guidance. The ghs has been implemented in the eu by regulation ec no 12722008 on classification, labelling and packaging of substances and mixtures the clp regulation. Ghs pictograms and hazard classes the recently updated hazard communication standard hcs requires certain pictograms be included on manufacturer and supplier labels of chemical containers to warn you of potential hazards of exposure. Hazard symbols and hazard pictograms chemical classification.
Sds complies with oshas hazard communication rule 29, cfr 1910. Classification and labelling clpghs internal market. Nphenylaminomethyltriethoxysilane safety data sheet print date. The clp hazard pictograms are very similar to those used in the old labelling system and appear in the shape of a diamond with a distinctive red border and white. There are 9 pictograms used in the new labeling system to convey the health, physical and environmental hazards. Pesticides, biocides, petrol, turpentine, diesel examples of precautionary statements. The new approved pictograms will be added periodically to the annexes of this guidance. May react pictogram explosively even in the absence of air. If contact with clothes and skin, rinse with water. In urgent cases, please submit your question through the contact form. Pictograms are intended to convey specific information about the hazards of a chemical. How to design warning infographics using transport hazard. The pictograms on the right are part of the new globally harmonized system ghs of classification and labeling.
Gas a no additional h230 additional hazard statement. Accordingly, the classification of your substance or mixture determines the hazard pictograms that should be displayed on your label, as set out in parts 2 physical hazards, 3 health hazards and 4 environmental hazards of annex i to clp clp article 19. The globally harmonized system of classification and labelling of chemicals ghs is an internationally agreedupon standard managed by the united nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Recognise the new ghs hazard pictograms and hazard statements. The deadline for substance classification according to the new rules was 1 december 2010.
The ghs is an acronym for the globally harmonized system of classification and labeling of chemicals. The pictograms help us to know that the chemicals we are using might cause harm to people or the environment. Very toxic to aquatic life, with longlasting effects toxic to aquatic life, with longlasting effects examples of where we may see it. Oregonosha peso hazard communication ghs 10 precautionary statements supplier identification labels shall have product identifier pictograms signal word hazard statements actual labels will be different from the one shown here. Grantee materials by topic occupational safety and health. The ghs chemical hazard pictograms are intended to provide the basis for or to replace national systems of hazard pictograms. The label of a hazardous substance or mixture includes pictograms, signal words, hazard statements, precautionary statements, and supplemental statements.
Subject to article 33, hazard pictograms shall fulfil the requirements laid down in section 1. This pictogram represents gases or liquids that oxidize, or lose. Ghs hazard pictogram consists of a standard hazard symbol placed to the shape of a red diamond with a white background. Whmis pictograms, hazard classes, and hazard categories pictogram associated hazard s hazard descriptions general safe work practices the flame pictogram is used for the following classes and categories. If medical advice is needed, have product container or label at hand. The rules they have to follow when they are classifying will change though, and a new set of hazard pictograms quite similar to the old ones are used. The clp regulation has introduced a new classification and labelling system for hazardous chemicals in the european union. Changes to chemical labels and sds euosha europa eu requirements. Core elements of the ghs include standardized hazard testing criteria, universal warning pictograms. On labels, the pictograms are accompanied by signal words. Globally harmonized system pictograms download as a pdf globally harmonized system of classification and labelling of chemicals ghs is an internationally agreedupon standard managed by the united nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. The diamondshaped pictograms indicate the nature of the hazard s associated with the use of a hazardous substance or mixture. The existing legislation on classification, labelling and packaging has been agreed at european union level and, from 2015, will be directly applied on all eu member states, including the uk.
A hazard pictogram is a pictorial presentation of a particular hazard. Hazard and precautionary information this document describes a procedure for manufacturers and suppliers to determine the pictograms, signal word, and hazard and precautionary statements required. Defining health, physical and environmental hazards of chemicals. Listing of corresponding hazard categories for each image. Ghs hazard pictograms solution from the conceptdraw solution park includes the set of standardized ghs hazard pictograms.
The label shall include the relevant hazard pictogram s, intended to convey specific information on the hazard concerned. Hazard pictograms alert us to the presence of a hazardous chemical. Distinguish between the ghs hazard classification categories recognise the new ghs hazard pictograms and hazard statements state what information must be provided on labels and packaging. Nphenylaminomethyltriethoxysilane safety data sheet sip6723. Under the clp regulation, pictograms with a red diamond on a white background replace the orange squares from the old system. State what information must be provided on labels and packaging. Hazard pictograms form part of the international globally harmonized system of classification and labelling of chemicals ghs. The echa website is temporarily down for maintenance.
Distinguish between the ghs hazard classification categories. Hazard communication standard pictogram as of june 1, 2015, the hazard communication standard hcs will require pictograms on labels to alert users of the chemical hazards to which they may be exposed. Global h monized system ghs pictograms and hazards ccohso canadian centre for occupational health and safety 18006684284 ohs. Consumer understanding of the safety label and pictograms. Changes to chemical labels and sds eu osha europa eu requirements. Signal code hazard statements hazard class category. Each pictogram consists of a symbol on a white background framed within a red border and represents a distinct hazard s. Hazard communication standard and the globally harmonized system. Minimum dimensions of labels and diamond pictograms in. As a first step, in addition to the industry perspective, insights were obtained from qualitative consumer research and from exchanges with medical experts a. Qrd guidance on the use of approved pictograms on the. The ghs symbols have been incorporated into pictograms for use on the ghs label.
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